Battery Engineering Insights

Overview

Explore technical articles from UnityVolt Solutions covering battery materials, cell testing, degradation modelling, pack design, techno-economic analysis, safety, and emerging battery technologies.

These insights are designed to help engineers, researchers, start-ups, investors, and technology teams connect battery science with practical engineering and commercial decision-making.

We also welcome contributions from researchers, engineers, and academics. If you are interested in writing a technical article or joining the UnityVolt Affiliate program, please get in touch.

Featured Series: Materials Characterization for Li-ion Cathodes

This 8-part series explains how materials characterization techniques are used to understand Li-ion cathode structure, morphology, composition, surface chemistry, thermal stability, and links to cell-level performance.

Muthu Krishna and Rupa Kasturi Palanisamy Muthu Krishna and Rupa Kasturi Palanisamy

2.4. Technical Due Diligence in LFP Cathode-Material Sourcing

An introduction to technical due diligence in LFP sourcing, covering supplier datasheets, independent powder characterisation, representative electrode and cell testing, manufacturing capability and supplier-quality assessment.

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Muthu Krishna and Rupa Kasturi Palanisamy Muthu Krishna and Rupa Kasturi Palanisamy

2.3. A Brief History of LFP Cathode Material Development

A concise history of LFP cathode-material development, from its discovery and early conductivity limitations to carbon coating, nanoscale engineering, patent changes, industrialisation and the informal Gen 1–5 evolution.

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Muthu Krishna and Rupa Kasturi Palanisamy Muthu Krishna and Rupa Kasturi Palanisamy

2.2. Cathode Materials 101

A practical introduction to layered, spinel and polyanionic cathode materials, explaining how crystal structure and composition shape the trade-offs between energy density, power, lifetime, safety and cost.

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Dr. Rupa Kasturi Palanisamy Dr. Rupa Kasturi Palanisamy

1.8. Summary - Linking Characterisation to cell KPIs

A practical summary linking cathode-powder morphology, composition, crystal structure, surface chemistry, nanostructure, porosity and thermal behaviour to cell-level KPIs including energy density, power, lifetime, safety and cost.

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Dr. Rupa Kasturi Palanisamy Dr. Rupa Kasturi Palanisamy

1.7. Advanced Methods (AFM, XAS, NMR)

An overview of advanced techniques used when conventional characterisation is insufficient. AFM, XAS and solid-state NMR provide deeper insight into nanoscale surfaces, element-specific atomic environments, lithium occupation and local structural changes.

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Dr. Rupa Kasturi Palanisamy Dr. Rupa Kasturi Palanisamy

1.6. Physical & Thermal Properties (BET & DSC/TGA)

Explore how gas adsorption, BET, DSC and TGA assess specific surface area, accessible porosity, thermal reactions and carbon content, and how these properties relate to electrode processing, rate performance and material stability.

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Dr. Rupa Kasturi Palanisamy Dr. Rupa Kasturi Palanisamy

1.5. Nanostructure Imaging (TEM & HRTEM)

Discover how TEM and HRTEM reveal primary-particle structure, lattice fringes, interfaces, defects and nanoscale coatings, and why these features can influence resistance, rate capability and cycle life.

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Dr. Rupa Kasturi Palanisamy Dr. Rupa Kasturi Palanisamy

1.4. Vibrational Spectroscopy (Raman & FTIR)

Learn how Raman and FTIR provide complementary information about local bonding, structural disorder, phosphate vibrations, surface residues and carbon coatings in Li-ion cathode materials.

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Dr. Rupa Kasturi Palanisamy Dr. Rupa Kasturi Palanisamy

1.3. Structural & Surface Chemistry (XRD & XPS)

Explore how XRD identifies crystal structure and crystalline secondary phases, while XPS examines surface composition and oxidation states. Together, they help assess cathode-material quality, stability and potential performance risks.

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Dr. Rupa Kasturi Palanisamy Dr. Rupa Kasturi Palanisamy

1.2. Morphology & Composition (FE-SEM & EDS)

Learn how FE-SEM and EDS reveal cathode-particle morphology, agglomeration and elemental distribution, and how these powder characteristics can influence electrode processing, active-material utilisation, rate capability and manufacturing consistency.

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Dr. Rupa Kasturi Palanisamy Dr. Rupa Kasturi Palanisamy

1.1. Materials Characterisation 101 for Li-ion Cell Cathodes

An introduction to the main techniques used to characterise Li-ion cathode powders, and how morphology, crystal structure, surface chemistry and thermal behaviour connect to electrode processing and cell performance.

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